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STM studies of cyclohexene hydrogenation/dehydrogenation and its poisoning by carbon monoxide on Pt(1 1 1)

โœ Scribed by Max Montano; Miquel Salmeron; Gabor A. Somorjai


Book ID
108279315
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
858 KB
Volume
600
Category
Article
ISSN
0039-6028

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The dehydrogenation of methanol on Pt(1 1 1)/water and Pt(1 1 1)/vacuum interfaces was investigated by using ab initio theoretical calculations. Possible reactive intermediate structures were optimized, and energetically favorable reaction pathways were traced at these two interfaces. When all produ