Stimulated echo description of coherent Raman beat EPR spectroscopy
โ Scribed by Eric Hoffmann; Arthur Schweiger
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 870 KB
- Volume
- 220
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
An analytical expression describing the evolution of an electron-nuclear spin system with anisotropic hyperfine coupling during selective microwave excitation is derived. The approach is applied to the two-pulse coherent Raman beat (CRB) EPR experiment, and is shown to be valid far beyond the linear
Coherent Raman beats (CRB) resulting from 14N hyperfine interactions have been observed in the EPR spectrum of the S = 1/2 state of a mixed valence di-lx-oxo bridged Mn(III, IV) bipyridyl dimer at X-band (9 GHz) and the results compared with those obtained from three-pulse electron spin echo envelop