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Stille Cross-Coupling Reactions with Tin Reagents Supported on Ionic Liquids

✍ Scribed by Phuoc Dien Pham; Jürgen Vitz; Cécile Chamignon; Arnaud Martel; Stéphanie Legoupy

Book ID
102177683
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
489 KB
Volume
2009
Category
Article
ISSN
1434-193X

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Catalyzed cross-coupling of allyl bromid
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The reaction of ally1 bromides with ally1 tin reagents, catalyzed by palladium or zinc chloride gives cross-coupled products without allylic transpostion in the ally1 halide partner but with predominate allylic rearrangement from the tin partner. The synthesis of compounds containing the polyisopre