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Stille Cross-Coupling Reaction of Polyfluorovinylstannanes. Stereospecific Synthesis of Polyfluoro-alkenes and -α,β-unsaturated Ketones.

✍ Scribed by Yanchang Shen; Guoping Wang


Book ID
101954739
Publisher
John Wiley and Sons
Year
2004
Weight
100 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract (__E__)‐α‐Arylsulfanylvinylstannanes react with acyl halides in the presence of a catalytic amount of Pd(PPh~3~)~4~ and CuI cocatalyst to give stereoselectively the corresponding (__Z__)‐α‐arylsulfanyl‐α,β‐unsaturated ketones in good yields. © 2009 Wiley Periodicals, Inc. Heteroatom Che