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Steroids. VIII. The Beckmann Rearrangement of 2-Oximinocholesta-4,6-dien-3-one. The Synthesis of Some 2,3-Secocholesta-4,6-dienes

✍ Scribed by Cava, M; Ahmed, Q


Book ID
125967739
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
557 KB
Volume
33
Category
Article
ISSN
0022-3263

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Synthesis of cyclohepta-4,6-diene-1,2,3-
✍ Mosahiro Hirama; ShΓ΄ ItΓ΄ πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 French βš– 188 KB

In the preceeding paper, we hove described successful synthesis of p-tropoquinone, cyclohepto-3,6diene-1,2,5+ione (1). The success encouraged us to prepare hitherto unknown o-tropoquinone CL, a seven-membered y&-triketone analogous to o-benzoquinone. In this paper, we report the synthesis of its sim