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Steroids. I. 3-Thio-enol Ethers of Δ 4 -3-Keto Steroids

✍ Scribed by Rosenkranz, G.; Kaufmann, St.; Romo, J.

Book ID: 120595230
Publisher: American Chemical Society
Year: 1949
Tongue: English
Weight: 791 KB
Volume: 71
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01179a031

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IT is generally admitted that the greater stability of A2 -over A3-5asteroidal enes determines the A2 structure of 3-keto-Z-steroid enol derivatives.ly2 This structure was actually proved for cholestanone ethyl enol ether, 3 prepared by both pyrolysis of diethylaceta14 and partial hydrogenation of c