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Steroidal α,β-epoxyketones. IV. Synthesis of the isomeric 6β-Bromo-4,5-epoxycholestan-3-ones

✍ Scribed by Collins, DJ; Hobbs, JJ

Book ID
126268178
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1965
Tongue
English
Weight
701 KB
Volume
18
Category
Article
ISSN
0004-9425

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α,β -epoxyketone chemistry, II: reaction
α,β -epoxyketone chemistry, II: reaction of HCl and HBr with steroidal 4β,5β-epoxy-3-ones
✍ M. Neeman; J.S. O'Grodnick 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 223 KB

In Part I the reaction8 of HP with ateroldal a,p-epoxyketones were shown to occur reglospeoifically by two alternative modes, B or a\*, depending upon the eolvent employed.3 In neat CHC13, two model compound8 48,5aepoxy-178~hydroxy-endrosten-3-one lb end 4r,5a-epoxy-178-hydroxy-androeten-