𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Sterically hindered internal rotation in acyclic hydrocarbons: 2,5-dimethyl-3,4-diisopropyl-2,4hexadiene

✍ Scribed by David S. Bomse; Thomas Hellman Morton

Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
229 KB
Volume
15
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Hindered rotation about single bonds baa been observed in a wide variety of molecules. Recent investigations of substituted butadienes have used nmr techniques to characterize this phenomenon, which renders these molecnles cbirall.

We wish to report the preparation of hydrocarbons~and~, substituted dienes that exhibit unusually high barriers to rotation about carbon-carbon single bonds.

πŸ“œ SIMILAR VOLUMES

Sterically hindered internal rotation in
Sterically hindered internal rotation in acyclic hydrocarbons: Tetraisopropylethylene
✍ David S. Bomse; Thomas Hellman Morton πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 French βš– 216 KB

In continuation of our studies of sterically crowded, acyclic hydrocarbons with hindered rotation about carbon-carbon single bondsI, we have prepared tetraisopropylethylene, BL, and its tetradeuterio 2 analogue, lb, by the reductive coupling reaction of McMurry and Fleming, reaction 1. Compound&, wh

ChemInform Abstract: Homolytic Cyclizati
ChemInform Abstract: Homolytic Cyclization of 1,3-Propanedithiol into 1,2-Dithiolane in the Presence of 2,5-Dimethyl-2,4-hexadiene.
✍ D. V. DEMCHUK; G. I. NIKISHIN πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v