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Sterically Demanding Phosphinimides: Ligands for Unique Main Group and Transition Metal Chemistry

✍ Scribed by Douglas W. Stephan


Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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Abstract

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Synthesis of (Indenylidene)phosphoranes
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Bridging ligands / Constrained geometry catalysts / Cyclopentadienyl ligands / Isoelectronic analogues / Isolobal relationship / Phosphoranes / Phosphorus ylides / Indenyl / Sodium IndPPh 2 (1) reacts with RCH 2 Br to form the phosphonium salts [RCH 2 P(Ph) 2 Ind] + Br -(2: R = Ph; 3: R = C 6 F 5 )