Sterically crowded diphosphinomethane ligands: molecular structures, UV-photoelectron spectroscopy and a convenient general synthesis of tBu2PCH2PtBu2 and related speciesDedicated to Professor Roald Hoffmann on the occasion of his 65th birthday.Electronic supplementary information (ESI) available: photoelectron spectra for compounds 1–6, ORTEP diagrams for compounds 1–3 and 5–9+, calculated minimum structures (UB3LYP/6-31G**) and structural parameters for two forms of the radical cation dmpm. See http://www.rsc.org/suppdata/nj/b2/b210114a/

✍ Scribed by Eisenträger, Frank; Göthlich, Alexander; Gruber, Irene; Heiss, Helmut; Kiener, Christoph A.; Krüger, Carl; Ulrich Notheis, J.; Rominger, Frank; Scherhag, Gunter; Schultz, Madeleine; Straub, Bernd F.; Volland, Martin A. O.; Hofmann, Peter

• Book ID: 120371284
• Publisher: Royal Society of Chemistry
• Year: 2003
• Tongue: English
• Weight: 376 KB
• Volume: 27
• Category: Article
• ISSN: 1144-0546
• DOI: 10.1039/b210114a