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Sterically Controlled Pathways in the Reaction of 2,4,6-Tris(isopropyl)benzenesulfonyl Azide and [Pd2Cl2(dppm)2]

✍ Scribed by Gábor Besenyei; László Párkányi; Isabella Foch; László I. Simándi


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
106 KB
Volume
112
Category
Article
ISSN
0044-8249

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Steric hindrance in the synthesis and pr
✍ György Keglevich*; László Toke; Zsolt Böcskei; Veronika Harmat 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 210 KB 👁 1 views

Steric hindrance was observed during the oxidation of 2,4,6-tri-tert-butylphenylphosphole to the P oxide and in the dimerization of this latter species to the corresponding phosphanorbornene derivative. Single-crystal X-ray analysis of the dimer revealed considerable steric crowding around the P ato