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Steric tuning of C2-symmetric chiral N-heterocyclic carbene in gold-catalyzed asymmetric cyclization of 1,6-enynes

✍ Scribed by Ken-ichi Yamada; Yasumasa Matsumoto; Khalid B. Selim; Yasutomo Yamamoto; Kiyoshi Tomioka


Book ID
113929431
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
349 KB
Volume
68
Category
Article
ISSN
0040-4020

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πŸ“œ SIMILAR VOLUMES


Chiral carbene approach to gold-catalyze
✍ Yasumasa Matsumoto; Khalid B. Selim; Hirotsugu Nakanishi; Ken-ichi Yamada; Yasut πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 263 KB

Chiral C 2 -symmetric N-heterocyclic carbenes (NHCs) were tested for their stereocontrolling abilities in gold(I)-catalyzed asymmetric cyclization of 1,6-enynes giving the corresponding cyclopentane derivatives with moderate enantioselectivity of up to 59%.

ChemInform Abstract: Chiral Carbene Appr
✍ Yasumasa Matsumoto; Khalid B. Selim; Hirotsugu Nakanishi; Ken-ichi Yamada; Yasut πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 2 views

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