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Steric retardation in activated nucleophilic aromatic substitution. The reactions of fluoro-4-nitrobenzene with some methyl-substituted piperidines in dimethyl sulfoxide.

✍ Scribed by Francesco Pietra; Del Cima Francesco

Publisher: Elsevier Science
Year: 1966
Tongue: French
Weight: 202 KB
Volume: 7
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)70058-x

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✦ Synopsis

Recently Suhr has reported (I) that the relative rates for the reactions of fluoro-4-hitrobenzene with piperidine, 2-methylpiperidine and cis-2,6_dimethylpiperidine* at 25°C in dimethyl sulfoxide (DKSO) are 30, 1.5 and 1, respectively.

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