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Steric rate enhancement in the Chapman rearrangement

✍ Scribed by Relles, Howard M.


Book ID
121861299
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
719 KB
Volume
33
Category
Article
ISSN
0022-3263

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Vibrational enhancement of the reaction
✍ I. Schechter; R. Kosloff; R.D. Levine πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 496 KB

The cone or acceptance for H+H= reactive collisions is shown Lo open up upon strelching of the H, bond. AL a given wtmslational energy, the sreric faclor is thus much larger for vibrzkonally cxcircd rcngems as demonswatcd by class&l IrajccLoq compulorions for H+ D?(U) and D+Hz(o). AI a given lolaI c