Steric enhancement of resonance. IV. Absorption spectra of N-alkyl and N,N-dialkylpicramides
β Scribed by Kamlet, Mortimer J.; Hoffsommer, John C.; Minesinger, Richard R.; Adolph, Horst G.
- Book ID
- 126854218
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 578 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Structurally related acyclic and cyclic __N__βnitrosoβ__N__βalkyl amino acids were prepared and their ^1^H, ^13^C and ^15^N NMR spectra were investigated. The changes in the ^13^C NMR spectra of the __N__βnitroso Ξ±βamino acids after dissolving in solvents suggest that they posses the __
The first ESR spectral data for the title amidyl radicals are reported They are conslstenttnth TI electronic ground states Recent e (RwC(=O)Z, Z=alkyl the exact geometry lectron spin resonance (ESR) studies indicate that N-alkylcarboxamldyl radicals