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Steric, Electronic, and Secondary Effects on the Coordination Chemistry of Ionic Phosphine Ligands and the Catalytic Behavior of Their Metal Complexes

✍ Scribed by Dr. Dennis J. M. Snelders; Prof. Dr. Gerard van Koten; Prof. Dr. Robertus J. M. Klein Gebbink


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
712 KB
Volume
17
Category
Article
ISSN
0947-6539

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## Abstract Rate constants for the hydrolysis (__k__~h~) of six different amines in __trans‐__[Co((BA)~2~en)(amine)~2~]ClO~4~ complexes (amine = aniline 1a, para‐toluidine 1b, benzylamine 1c (primary amines), pyrrolidine 2a, piperidine 2b, morpholine 2c (secondary amines), and (BA)~2~en = Bisbenzoy