Steric effects of ortho substituents in reactions of phenols and phenolates with polyfluoroketones
โ Scribed by V. I. Dyachenko; M. V. Galakhov; A. F. Kolomiets; A. V. Fokin
- Book ID
- 112444586
- Publisher
- Springer
- Year
- 1989
- Tongue
- English
- Weight
- 488 KB
- Volume
- 38
- Category
- Article
- ISSN
- 1573-9171
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Substituent effects in the reactivities of phenols towards polyacrylonitrile radicals have been studied in terms of Swain and Luptons' field (FR) and resonance (Rk) components of the substituent parameters and the unique positional weighting factors (fj and r j) proposed by Williams and Norrington,
The standard ( p o = 0.1 MPa) molar enthalpies of formation f H o m (l, or cr) at the temperature 298.15 K were measured by means of combustion calorimetry for 2, 3,6-tri-methylphenol, 2,4,6-tri-methylphenol, 2,6-di-iso-propylphenol, 2-tert-butyl-6-methylphenol, 2-tert-butyl-4,6-di-methylphenol, 2,6