Stereoisomeric effects on mass spectral
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A. P. Rothwell; R. G. Cooks; T.-V. Singh; L. De CΓ‘rdenas; H. Morrison
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Article
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1985
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John Wiley and Sons
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English
β 574 KB
Stereoelectronic factors allow facile CI' atom loss from the ero-6-chloro-2-norbornanone radical cation but not from the endo-6-epimer. The predominant primary reaction in the endo-6 and in the m o d and endo-5 compounds is HCI elimination. While C1' e l i n a t i o n occurs with skeletal reorganiza