Steric Effects in the Formation of Copper and Cobalt Complexes with the Epimeric Salicylidenementhylamines
โ Scribed by HOCKING, C. S.; ROBERTSON, W. G. P.; WEST, B. O.
- Book ID
- 109586368
- Publisher
- Nature Publishing Group
- Year
- 1955
- Tongue
- English
- Weight
- 202 KB
- Volume
- 176
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/176832a0
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๐ SIMILAR VOLUMES
## Abstract Rate constants for the hydrolysis (__k__~h~) of six different amines in __transโ__[Co((BA)~2~en)(amine)~2~]ClO~4~ complexes (amine = aniline 1a, paraโtoluidine 1b, benzylamine 1c (primary amines), pyrrolidine 2a, piperidine 2b, morpholine 2c (secondary amines), and (BA)~2~en = Bisbenzoy
## Abstract A series of tetraโ__N__โalkylated 1,4,8,11โtetraazacyclotetradecanes have been synthesized and their complexation potential towards Ni^2+^ and Cu^2+^ studied. In the case of sterically demanding alkyl substituents, such as iโPr, PhCH~2~, or 2โMeC~6~H~4~CH~2~, no metal complexes are form