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Steric effects in the 17O NMR spectroscopy of aromatic methyl ethers

✍ Scribed by M. A. Wysocki; P. W. Jardon; G. J. Mains; E. J. Eisenbraun; D. W. Boykin

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 408 KB
Volume: 25
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260250412

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✦ Synopsis

0 NMR spectroscopic data (natural abundance) were obtained for 19 methoxy-aromatic compounds: a series of substituted anisoles with a single ortho substituent, a series of 2,Q-disubstituted anisoles, a series of 3-substituted-1, 2-dimethoxybenzenes and three multi-substituted anisole derivatives. The chemical shifts of the highly hindered methoxy compounds are related to previously reported regiochemistry, spectroscopic results and from theoretical calculations for these compounds.

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