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Steric effects in ortho-substituted triarylmethanes

โœ Scribed by Sabacky, M. J.; Johnson, Suzanne M.; Martin, James Cullen; Paul, Iain C.


Book ID
126916655
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
399 KB
Volume
91
Category
Article
ISSN
0002-7863

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Steric and electronic effects on the oxi
โœ D.G. Lee; M. Raptis ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 483 KB

A study has been made of the oxidation of a number of substituted benzhydrols by chromic acid in aqueous acetic acid. The reaction rate constants are linearly proportional to the KR+ values of the alcohols. ortho-Substitution increases the rate of reaction and reduces the magnitude of the primary ki