Use of Borinium Ions as Probes of Steric
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John J. Isbell; Jennifer S. Brodbelt
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Article
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1996
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John Wiley and Sons
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English
⚖ 357 KB
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The relative free energies of binding of the dimethoxy borinium ion to several substituted pyridines were determined using the equilibrium method and were found to correlate we11 with relative gas-phase basicities except in the case in which different sterics were present near the site of cation att