✦ LIBER ✦

Steric Effects in Elimination Reactions. XII. The Reaction of Potassium t-Butoxide with Cyclic Tosylates. The Effect of Structure on the Rate and Direction of Eliminations in Cyclic Systems 1

✍ Scribed by Brown, Herbert C.; Klimisch, Richard L.

Book ID: 126116525
Publisher: American Chemical Society
Year: 1966
Tongue: English
Weight: 530 KB
Volume: 88
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00959a019

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Steric Effects in Elimination Reactions.

Steric Effects in Elimination Reactions. XI. The Reaction of Potassium t-Butoxide with 2-Butyl and t-Amyl Halides. The Effect of the Halogen on the Direction of Elimination 1

✍ Brown, Herbert C.; Klimisch, Richard L. 📂 Article 📅 1966 🏛 American Chemical Society 🌐 English ⚖ 641 KB

Mechanisms of Elimination Reactions. VII

Mechanisms of Elimination Reactions. VIII. The Effect of Added Dimethyl Sulfoxide on Rates, Isotope Effects, and Substituent Effects in the Reaction of 2-Arylethyl Bromides with Potassium t -Butoxide in t -Butyl Alcohol

✍ Cockerill, Anthony F.; Rottschaefer, Susan.; Saunders, William H. 📂 Article 📅 1967 🏛 American Chemical Society 🌐 English ⚖ 609 KB

Hydroboration. XXVIII. The hydroboration

Hydroboration. XXVIII. The hydroboration of 3-cyclopentenyl derivatives containing representative substituents. Directive effects and the elimination reaction in a cyclic system

✍ Brown, Herbert C.; Knights, Evord F. 📂 Article 📅 1968 🏛 American Chemical Society 🌐 English ⚖ 764 KB

Nonlinear Hammett plot. Substituent effe

Nonlinear Hammett plot. Substituent effects in the substitution and elimination-rearrangement reactions of 1,1-diaryl-2-bromoethenes with potassium tert-butoxide in an aprotic solvent

✍ Bender, Daniel F.; Thippeswamy, Thuduma.; Rellahan, William L. 📂 Article 📅 1970 🏛 American Chemical Society 🌐 English ⚖ 717 KB

The kinetics of the gas phase intramolec

The kinetics of the gas phase intramolecular elimination of isobutene from 2-d1-triisobutylaluminum and the deuterium isotope effect in reactions involving cyclic transition states

✍ Kurt W. Egger 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 654 KB

The intramolecular elimination of isobutene from 2-d,-triisobutylaluminum has been studied in the gas phase for temperatures ranging between 102.4 and 184.6'C. The reaction is apparently homogeneous and obeys the first order rate law, yielding the following Arrhenius relationship: log kelim (sec-')

Mechanisms of elimination reactions. IX.

Mechanisms of elimination reactions. IX. Effect of added dimethyl sulfoxide on rates and sulfur isotope effects in the reaction of 2-phenylethyldimethylsulfonium bromide with hydroxide ion in water

✍ Cockerill, Anthony F.; Saunders, William H. 📂 Article 📅 1967 🏛 American Chemical Society 🌐 English ⚖ 387 KB