Steric Control of the Electronic Ground
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Nayan K. Solanki; Eric J. L. McInnes; Frank E. Mabbs; Sanja Radojevic; Mary McPa
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Article
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1998
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John Wiley and Sons
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English
⚖ 110 KB
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Replacing the 3- and 3''-protons of the ligand 2,6-di(pyrazol-1-yl)pyridine L by mesityl groups changes the electronic ground state of [Cu(L) ] complexes from {d x 2-y 2} to {d z 2} . This is the best example so far for a "homoleptic" Jahn-Teller-compressed six-coordinate Cu complex.