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Steric control in Ziegler-Natta catalysts: An analysis of nonbonded interactions at model catalytic sites

✍ Scribed by Paolo Corradini; Vincenzo Barone; Roberto Fusco; Gaetano Guerra


Book ID
113176878
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
778 KB
Volume
77
Category
Article
ISSN
0021-9517

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Analysis of models for the Ziegler-Natta
✍ P. Corradini; V. Barone; R. Fusco; G. Guerra πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 English βš– 658 KB

Abstrmct--The model proposed by Cossee for Ziegler-Natta polymerization of propene is re-examined by computing the non-bonded energies for all sets of possible internal coordinates of the atoms at the catalytic site. For catalytic sites in the bulk of ( 110) surfaces of TiCI3-~, it is possible to ex