Steric and kinetic effects of changing solvent and reagent in grignard reactions on some 4-substituted cyclohexanones
β Scribed by Claudia Cianetti; Giorgio Di Maio; Vito Pignatelli; Pietro Tagliatesta; Elisabetta Vecchi; Errico Zeuli
- Book ID
- 108372749
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 682 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4020
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## Abstract Kinetic studies are reported for the reactions with aniline in benzene of a series of Xβphenyl 2,4,6βtrinitrophenyl ethers [X = H; 2β, 3β, 4βCH~3~; 2,4β, or 2,6β(CH~3~)~2~] aβf, and the results compared with those of the corresponding nitro derivatives. In the methyl series, kinetic dat
Although the reaction of substituted fluoroolefins with nucleophiles, such as ethoxide, has received considerable attention in recent years (l), little is known concerning the subsequent attack by excess Grignard reagent on the initially formed substitution product in these systems.