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Steric and electronic substituent effects in tertiary alkyl peroxide decompositions

✍ Scribed by William H. Hendrickson; Chi C. Nguyen; Jackie T. Nguyen; Kim T. Simons


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
218 KB
Volume
36
Category
Article
ISSN
0040-4039

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## Abstract When the __Hammett‐Taft__ equation log (__k/k__~o~)=ρ^q^ Β· Οƒ is applied to the solvolysis of the 3‐substituted propyl bromides **6a‐6i** in ethanol/water 4:1 __(v/v)__ log __k__ correlates linearly with Οƒ except in cases where R exerts an anchimeric effect. The reaction constant ρ^q^ fo