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Steric and electronic limitations of the SRN1 reaction between p-nitrobenzylic substrates and tertiary carbanions

✍ Scribed by Bruce D Jacobs; Soon-Jae Kwon; Leslie D Field; Robert K Norris; David Randles; Karen Wilson; Timothy A Wright

Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 235 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)98673-8

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✦ Synopsis

The ~~1 reaction between sterically hindered p-nitrobenzylic substrates and tertiary carbanions gives C-alkylated products whose yields depend on the steric bulk of both the benzylic substrate and the carbanion, and on the nature of the groups in the carbanion.

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