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Steric and electronic effects on the stereochemistry of the alkaline hydrolysis of acyclic dialkoxyphosphonium salts. Pseudorotation of intermediates in phosphorus ester reactions

✍ Scribed by DeBruin, Kenneth E.; Petersen, John R.


Book ID
125966999
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
1024 KB
Volume
37
Category
Article
ISSN
0022-3263

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## Abstract It can be shown that alkaline hydrolysis of four‐coordinated phosphorus (P^IV^) compounds is substantially accelerated if the trigonal‐bipyramidal (TBP) five‐coordinated phosphorus (P^V^) intermediate in the reaction can exhibit conformational transmission. With the compounds 5a‐c, it w