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Steric and electronic effects on nitrogen-15 chemical shifts of saturated aliphatic amines and their hydrochlorides

✍ Scribed by Duthaler, Rudolf O.; Roberts, John D.


Book ID
126771634
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
770 KB
Volume
100
Category
Article
ISSN
0002-7863

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## Abstract The ^17^O NMR chemical shifts of 14 __N__‐methylpiperidine‐__N__‐oxides and five __N__‐methyltetradecahydroacridine‐__N__‐oxides were measured. The effects of steric factors, such as γ‐__gauche__ and 1,3‐__syn__‐axial interactions of the N^+^β€”O^βˆ’^ oxygen, on the ^17^O chemical shifts ar