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Steric and electronic effects of ligand variation on cobalt dioxygen catalysts

✍ Scribed by Corden, Barry B.; Drago, Russell S.; Perito, Richard P.

Book ID
126305058
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
651 KB
Volume
107
Category
Article
ISSN
0002-7863

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## Abstract Rate constants for the hydrolysis (__k__~h~) of six different amines in __trans‐__[Co((BA)~2~en)(amine)~2~]ClO~4~ complexes (amine = aniline 1a, para‐toluidine 1b, benzylamine 1c (primary amines), pyrrolidine 2a, piperidine 2b, morpholine 2c (secondary amines), and (BA)~2~en = Bisbenzoy