The kinetics and mechanism of the removal of M2+ from bis-(heptane-2,4,6-trionato)M(II) [M = Ni, Co] by ethylenediminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), 1,2-cyclohexanediamine-N, N, N', N'tetraacetic acid (CyDTA), and ethylenebis(oxyethylenenitri1o)tetraacetic acid (EGTA) have bee
β¦ LIBER β¦
Steric and conformational effects on the kinetics of ligand substitution in bis(salicylaldiminato)nickel(II) complexes
β Scribed by Schumann, Manfred.; Von Holtum, Angela.; Wannowius, Klaus J.; Elias, Horst.
- Book ID
- 120690710
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 890 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0020-1669
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Nickel(II) complexes of mono-and bis(macrocyclic) ligands are the products of a nickel(II)-assisted template reaction with 2,3,2-tet, melamine and formaldehyde [2,3,2-tet = bis-N,NΠ-(2-aminoethyl)propane-1,3-diamine; melamine = 2,4,6-triamino-1,3,5-triazine]. The structures of two four-coordinate, d