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Steric acceleration in the thermal decarbonylation of highly compressed norbornen-7-ones

✍ Scribed by R. McCulloch; A.R. Rye; D. Wege

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
225 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis

Norbornadien-'I-one 2 and its benzo-annellated derivatives are highly reactive molecules, which readily undergo thermal deoarbonylution to yield benzene and its benzo-annellated derivatives.1 Although the factors which contribute to the high reactivity of 4 and its derivatives have not been fully determined, they are apparently largely electronic in nature?

Norbornen-7-one 4 substituted nor~ornen-7-ones undergo thermal decarbonylation with varying ease. Thus locten-l-one is reactive, looeee monoxide give at while exo-trioyc10[3.2.1.

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