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Stereospecific Synthesis of Vinyl(phenyl)iodonium Tetrafluoroborates via Boron-Iodane Exchange of Vinylboronic Acids and Esters with Hypervalent Phenyliodanes

✍ Scribed by Masahito Ochiai; Mika Toyonari; Takema Nagaoka; Da-Wei Chen; Michio Kida

Book ID: 104257900
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 528 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)01571-2

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✦ Synopsis

Reactionof vinylboronicacidsendesterswithhypervaient phenyliodanes in the presence of BF-j-Et20 undergoes boron-icdsneexchangeat O "C in dichloromethane yielding vinyl(phenyl)iodoniumtetratluoroborates stereoaekctively withMentionof configuration. @ 1997ElsevierScienceLtd.

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