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Stereospecific Synthesis of Pseudocodeine: [2,3]-Sigmatropic Rearrangement Using Selenium Intermediates

✍ Scribed by Kshirsagar, Tushar A.; Moe, Scott T.; Portoghese, Philip S.


Book ID
127015407
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
33 KB
Volume
63
Category
Article
ISSN
0022-3263

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Stereospecific Synthesis of 1,2-Difuncti
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AbstractÐThermolysis of bis-thiocarbamates derived from but-3-yne-1,2-diols resulted in the formation of buta-1,3-dienes with carbamoylthio groups in positions 1 and 2 with good to excellent yields. The stereochemistry of the products is controlled by substituents at C-1 of the starting material and