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Stereospecific synthesis of erythro cinchona alkaloids from secologanin

✍ Scribed by Richard T Brown; Dale Curless

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 198 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)85384-8

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✦ Synopsis

A short, diastereoselective synthesis of (t)-dihydrocinchonine (7) and (-l-dihydrocinchonidine (8) from their biogenetic precursor, secologanin (la), and lepidine has been achieved in 28% overall yield.

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