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Stereospecific synthesis of a biologically active dehydro derivative of the C18-juvenile hormone of cecropia. New routes to a key C12-intermediate

✍ Scribed by E.J. Corey; John A. Katzenellenbogen; Steven A. Roman; Norman W. Gilman


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
229 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis


Two different stereospecific syntheses of tbe Cl8 -insect hormone of Cecropia have been reported from this Laboratory previously (1,2).

A critical intermediate in the first of these is 3-ethyl-'l-metbyl-

We now outliue two new stereospecific routes to this interesting bomo-trans, cis-2,6-nonadien-l-01 (I).