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Stereospecific synthesis of 1,4-dienes by cross-coupling of allyl halides with alkenylcopper intermediates from alkenyldialkylboranes

✍ Scribed by Brown, Herbert C.; Campbell, James B.


Book ID
126274623
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
381 KB
Volume
45
Category
Article
ISSN
0022-3263

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Stereospecific synthesis of a family of
✍ Fumio Sasaki; Takanori Endo; Masanori Noguchi; Kenji Kawai; Taichi Nakano πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 225 KB πŸ‘ 2 views

## Abstract Stereospecific synthesis of a family of novel (__E__)‐2‐aryl‐1‐silylalka‐1,4‐dienes or (__E__)‐4‐aryl‐5‐silylpenta‐1,2,4‐trienes via a cross‐coupling of (__Z__)‐silyl(stannyl)ethenes with allyl halides or propargyl bromide is described. In the reaction with allyl bromide, either a Pd(db