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Stereospecific synthesis and electronic absorption properties of cis- and trans-4-acetoxyisopulegone

โœ Scribed by Sheehan, John C.; Wilson, R. Marshall.


Book ID
125899623
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
743 KB
Volume
89
Category
Article
ISSN
0002-7863

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An efficient and versatile method for the stereospecific construction of a,v-cisand a,v-trans-disubstituted oxepane skeletons is described. Cyclization of the hydroxy epoxides promoted by a (Bu 3 Sn) 2 O/ Zn(OTf) 2 system proceeded via an S N 2 process and exo mode selectivity regardless of the conf