𝔖 Bobbio Scriptorium
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Stereospecific syntheses of erythro and threo 5-(1′.2′-Dihydroxyethyl)-3-aryl-oxazolidin-2-ones.

✍ Scribed by J.P Genet; A Denis; A Vilar (in part); A.R Schoofs; P Alard


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
239 KB
Volume
31
Category
Article
ISSN
0040-4039

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Condensation of 4-methylsulfonylaniline with aryl aldehyde in ethanol-tetrahydrofuran afforded the imino compound 3. 1,3-Cycloaddtion of diazomethane with compound 3 followed by oxidazation of the triazoline 4 with potassium permanganate gave 1-(4-methylsulfonylphenyl)-5-aryl-1,2,3-triazoles 5. Simi