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Stereospecific preparation of ethyl (E) and (Z)-3-aryl-e-phenylpropenoates by heck reaction

✍ Scribed by Marcial Moreno-Mañas; Montserrat Pérez; Roser Pleixats


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
261 KB
Volume
37
Category
Article
ISSN
0040-4039

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Stereospecific synthesis of (1E,3Z)- and
✍ V. Fiandanese; G. Marchese; G. Mascolo; F. Naso; L. Ronzini 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 264 KB

A new synthesis of stereodefined 1-trimeUlylsllyl-1,3-dlenes is described. The method is based on two sequential coupling reactions between Grlgnard reagents and the readily available (Z)-or (15)-l -bromo-2-phenylthloethene, In the presence of transition metal catalysts.