Stereospecific cleavage of carbon-transition metal o-bonds has recently received considerable attention. Halogen cleavage of the metal-carbon bond may occur with either inversion l-3 or retention3+ of configuration at carbon. In metal-for-metal exchange reactions, retention at carbon seems to be the
โฆ LIBER โฆ
Stereospecific palladium-promoted oxyamination of alkenes
โ Scribed by Baeckvall, Jan E.; Bjoerkman, Eva E.
- Book ID
- 120347116
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 759 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0022-3263
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We have recently reported on the palladium-promoted oxyamination' and aziridination 2 of olefins. These transformations were obtained by aminopalladation3 of the olefin followed by an oxidative cleavage of the palladium-carbon bond in the adduct. In the oxyamination study it was found' that vicinal