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Stereospecific palladium-promoted oxyamination of alkenes

โœ Scribed by Baeckvall, Jan E.; Bjoerkman, Eva E.


Book ID
120347116
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
759 KB
Volume
45
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


Stereospecific palladium(II)-lead(IV)-pr
โœ Jan-E. Bรคckvall ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 253 KB

Stereospecific cleavage of carbon-transition metal o-bonds has recently received considerable attention. Halogen cleavage of the metal-carbon bond may occur with either inversion l-3 or retention3+ of configuration at carbon. In metal-for-metal exchange reactions, retention at carbon seems to be the

Stereospecific palladium-promoted vicina
โœ Jan-E. Bรคckvall ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 238 KB

We have recently reported on the palladium-promoted oxyamination' and aziridination 2 of olefins. These transformations were obtained by aminopalladation3 of the olefin followed by an oxidative cleavage of the palladium-carbon bond in the adduct. In the oxyamination study it was found' that vicinal