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Stereospecific hydrogen-deuterium exchange via an enolate ion

โœ Scribed by Guthrie, Robert D.; Nicolas, Edgar C.

Book ID
126318038
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
303 KB
Volume
103
Category
Article
ISSN
0002-7863

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Enhanced gas-phase hydrogen-deuterium ex
Enhanced gas-phase hydrogen-deuterium exchange of oligonucleotide and protein ions stored in an external multipole ion reservoir
โœ Hofstadler, Steven A.; Sannes-Lowery, Kristin A.; Griffey, Richard H. ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 177 KB ๐Ÿ‘ 2 views

Rapid gas-phase hydrogen-deuterium (H-D) exchange from D 2 O and ND 3 into oligonucleotide and protein ions was achieved during storage in a hexapole ion reservoir. Deuterated gas is introduced through a capillary line that discharges directly into the low-pressure region of the reservoir. Following