Stereospecific alcohol elimination from dialkyl mesaconates under electron impact: Another example of a hidden hydrogen transfer

Mechanism of stereospecific alcohol elim

Mechanism of stereospecific alcohol elimination from cyclohexane trans-1,3-dicarboxylates under electron impact ionization

✍ A. Etinger; A. Idina; A. Mandelbaum 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 373 KB

Diesters of cyclohexaae trPns-l,3dicarboxylc acid give rise to major [ M -ROH] +' ions under electron impact ionization. A mass spectral study of the isomeric mixed methyl ethyl esters of the diacid, substituted by a methyl group at position 1 and deuterium labelled at position 3, indicates a stepwi