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Stereospecific acid-catalyzed rearrangement of 1,6-dimethylpentacyclo[6.4.0.02,7.03,10.06,9]dodecane-5,12-dione to a bisnordiadamantane

โœ Scribed by Hirao, Kenichi; Taniguchi, Mikio; Iwakuma, Takeo; Yonemitsu, Osamu; Flippen, Judith L.; Karle, Isabella L.; Witkop, Bernhard


Book ID
126188555
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
204 KB
Volume
97
Category
Article
ISSN
0002-7863

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The clemmensen reduction of pentacyclo [
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The Clenanensen reduction of pentacyclo[6.4.0.02~7.03,11.06~10], dodecane-9,12-dione unexpectedly led to the formation of pentacyclo[6.4.0. 02.6.05,9.04.12]-2-dodecanol and pentacyclo[6.4.0.02~7.03,11.06,10]dodecane-1,Gdiol as main products. Tetracyclo[6.4.0.05,9.04,12]dodecane-2,7dione and its corr