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Stereoselectivity of the intramolecular homolytic substitution in the induced decomposition of methacrylic-type peroxidic compounds: Tetrahedron


Book ID
104207511
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
46 KB
Volume
53
Category
Article
ISSN
0040-4020

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Synthesis of methacrylic-type peroxidic
✍ Daniel Colombani πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 958 KB

Various unsaturated peroxidic compounds have been prepared, characterized and inductively decomposed in various solvents to afford the corresponding oxiranes. The reaction proceeded by a radical chain mechanism and was initiated either by thermolysis of added t-but~-I peracetate at 110Β°C or AIBN at