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Stereoselectivity of the base-induced conversion of epoxides to allylic alcohols

✍ Scribed by Rickborn, Bruce; Thummel, Randolph P.

Book ID
127066393
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
476 KB
Volume
34
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Acid-catalysed isomerisation of epoxides
Acid-catalysed isomerisation of epoxides to allylic alcohols
✍ A. van Zon; R. Huis πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 438 KB

## Abstract The acid‐catalysed isomerisation of epoxides containing tertiary ring carbon atoms results in the selective formation of the corresponding allylic alcohols if the reaction is carried out in methylene chloride or chloroform in the presence of small quantities of sulfuric acid (< 10 mmol/