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Stereoselectivity of photo-oxidation at the C7double bond of isocembrol and its derivatives

โœ Scribed by N. I. Yaroshenko; V. A. Raldugin

Publisher
Springer
Year
1984
Tongue
English
Weight
525 KB
Volume
20
Category
Article
ISSN
0009-3130

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โœ Jean-Louis Reymond; Pierre Vogel ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 284 KB

An qJ?cient method has been developed for the stereoselective substitution of ## 7-oxabicyclo[2.2.l]hept-2-yl derivatives by protected amino group at C(S-exo) and hydroxy group at C(6-endo). The 7-oxabicyclo[2.2.1]hept-S-en-2-yl derivatives 1 -6 can be obtained optically pure.' Because of their b