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Stereoselectivity of Dienamine [4 + 2] Cycloadditions Synthesis of Functionalised Decalins and Drimanes

✍ Scribed by Roger L. Snowden; Robert Brauehli; Manfred Wüst

Publisher
John Wiley and Sons
Year
1990
Tongue
German
Weight
781 KB
Volume
73
Category
Article
ISSN
0018-019X

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✦ Synopsis

l) C(2) C(3) C(4) C(4a) C(5) C(6) C(7) C(8) C(8a) CH, (R') CH, (R') CH,(R3) pound 7") 35.4 27.4 25.8 33.3 40.6 45.2 48.

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A Regioselective Cyclohexannulation Proc
A Regioselective Cyclohexannulation Procedure via Dienamine [4 + 2] Cycloaddition. Synthesis of Functionalised Decalins
✍ Roger L. Snowden; Simon M. Linder; Manfred Wüst 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 German ⚖ 892 KB

## 1. Introduction. the synthetic application of dienamines I [I] as Diels-Alder dienes is well documented'). The main features of their reactions with dienophiles are high reactivity and the fact that the R,N group controls the regiochemistry of the cycloaddition. For example, the use of electron-