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Stereoselectivity in the nucleophilic addition-type polymerization of α-amino acid N-caboxyanhydride initiated by diastereomeric dipeptide amines

✍ Scribed by H. Ohnishi; Y. Hashimoto; Y. Imanishi


Book ID
119069720
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
596 KB
Volume
3
Category
Article
ISSN
0141-8130

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Enantiomer selection in the addition rea
✍ Yutaka Hashimoto; Yukio Imanishi 📂 Article 📅 1981 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 813 KB

## Abstract In order to investigate the contribution from the chiral penultimate unit to the enantiomer selection in the activated __N__‐carboxyanhydride (NCA) polymerizations, the addition reaction to __N__‐[(S)‐methylbenzyl]glycine NCA of various α‐amino acid hydantoins activated by the tertiary